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JEE Main 202227 JulyEvening Shift
Exam
JEE Main
Year
2022
Date
27 July
Shift
Evening Shift
Subject
Chemistry
Chapter
Chemical Bonding and Molecular Structure

JEE Main 2022 · 27 July · Evening Shift · Chemistry · Chemical Bonding and Molecular Structure

Match List-I with List-II List-I List-II A Ψ _ MO = Ψ _ A - Ψ _ B I...

Match List-I with List-II

List-I List-II
A ΨMO=ΨA−ΨB{Ψ}_{MO} = {Ψ}_{A} - {Ψ}_{B} I Dipole moment
B μ=Q×r\mu = Q \times r II Bonding molecular orbital
C Nb−Na2\dfrac{{N}_{b} - {N}_{a}}{2} III Anti-bonding molecualr orbital
D ΨMO=ΨA+ΨB{Ψ}_{MO} = {Ψ}_{A} + {Ψ}_{B} IV Bond order

Options

  1. AA−II,B−I,C−IV,D−IIIA - II, B - I, C - IV, D - III
  2. BA−III,B−IV,C−I,D−IIA - III, B - IV, C - I, D - II
  3. CA−III,B−I,C−IV,D−IIA - III, B - I, C - IV, D - II
  4. DA−III,B−IV,C−II,D−IA - III, B - IV, C - II, D - I

Correct answer

C. A−III,B−I,C−IV,D−IIA - III, B - I, C - IV, D - II

Step-by-step solution

The molecular orbital σ formed by the addition of atomic orbitals is called the bonding molecular orbital while the molecular orbital σ* formed by the subtraction of atomic orbital is called antibonding molecular orbital.

The electron density in a bonding molecular orbital is located between the nuclei of the bonded atoms because of which the repulsion between the nuclei is very less while in case of an antibonding molecular orbital, most of the electron density is located away from the space between the nuclei. Infact, there is a nodal plane (on which the electron density is zero) between the nuclei and hence the repulsion between the nuclei is high.

List-I List-II
A ΨMO=ΨA−ΨB{Ψ}_{MO} = {Ψ}_{A} - {Ψ}_{B} I ABMOABMO
B μ=Q×r\mu = Q \times r II Dipole moment
C Nb−Na2\dfrac{{N}_{b} - {N}_{a}}{2} III Bond order
D ΨMO=ΨA+ΨB{Ψ}_{MO} = {Ψ}_{A} + {Ψ}_{B} IV BMOBMO
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