Quantrex Quantrex AcademyJEE · NEET · NDA PYQs with solutions Open app
JEE Main 202227 JuneEvening Shift
Exam
JEE Main
Year
2022
Date
27 June
Shift
Evening Shift
Subject
Chemistry
Chapter
Chemical Bonding and Molecular Structure

JEE Main 2022 · 27 June · Evening Shift · Chemistry · Chemical Bonding and Molecular Structure

Identify the incorrect statement for PCl _ 5 from the following.

Identify the incorrect statement for PCl5{PCl}_{5} from the following.Identify the incorrect statement for PCl _ 5 from the following.Identify the incorrect statement for PCl _ 5 from the following.

Options

  1. AIn this molecule, orbitals of phosphorous are assumed to undergo sp3d{sp}^{3}d hybridization.
  2. BThe geometry of PCl5{PCl}_{5} is trigonal bipyramidal.
  3. CPCl5{PCl}_{5} has two axial bonds stronger than three equatorial bonds.
  4. DThe three equatorial bonds of PCl5{PCl}_{5} lie in a plane.

Correct answer

C. PCl5{PCl}_{5} has two axial bonds stronger than three equatorial bonds.

Step-by-step solution

sp3d hybridization is shown in phosphorus penta chloride (PCl5). The grounds state and the excited state outer electronic configurations of phosphorus (Z=15) are represented below

Identify the incorrect statement for PCl _ 5 from the following.

Now the five orbitals (i.e., one s, three p and one d orbitals) are available for hybridization to yield a set of five sp3d hybrid orbitals which are directed towards the five corners of a trigonal bipyramidal as depicted in the below.

Identify the incorrect statement for PCl _ 5 from the following.

It should be noted that tall the bond angles in trigonal bipyramidal geometry are not equivalent. In PCl5 the five sp3d orbitals of phosphorus overlap with the singly occupied p orbitals of chlorine atoms to form five P-Cl sigma bonds. Three P-Cl bond lie in one plane and make an angle of 120o with each other; these bonds are termed as equatorial bonds. The remaining two P-Cl bonds-one lying above and the other lying below the equatorial plane, make an angle of 90o with the plane. These bonds are called axial bonds. As the axial bond pairs suffer more repulsive interaction form the equatorial bond pairs, therefore axial bonds have been found to be slightly longer and hence slightly weaker than the equatorial bonds; which makes PCl5 molecule more reactive.

Practice Chemical Bonding and Molecular Structure on Quantrex Academy →

More from Chemical Bonding and Molecular Structure

The correct order of dipole moments for the given species is JEE Advanced 2026Consider the following species: SOCl_2 , XeOF_4 , ClF_3 , ClF_5 , XeF_5^+ , SO_3^ 2… JEE Advanced 2026The correct order of ONO bond angle in the given species is JEE Advanced 2026Bromine trifluoride autoionizes to form BrF_2^ and BrF_4^ . The shapes of the cation and… JEE Main 2026Given below are two statements : Statement I : The number of compounds among SO _2 , SO… JEE Main 2026Given below are two statements : Statement I : F _2 O Statement II : SiF _4 , SnF _4 and… JEE Main 2026The pairs among A = [SO_3^ 2- , CO_3^ 2- ] , B = [O_2^ 2- , F_2] , C = [CN^-, CO] , D =… JEE Main 2026The covalent radii of atoms A and B are r_A and r_B , respectively. The covalent bond… JEE Main 2026 Full Chemical Bonding and Molecular Structure list All JEE Main PYQs