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JEE Main 20262 AprilEvening Shift
Exam
JEE Main
Year
2026
Date
2 April
Shift
Evening Shift
Subject
Chemistry
Chapter
Chemical Kinetics

JEE Main 2026 · 2 April · Evening Shift · Chemistry · Chemical Kinetics

Consider the reaction aX arrow bY , for which the rate constant at...

Consider the reaction aX→bYaX \rightarrow bY, for which the rate constant at 30°C30°C is 1×10−31 \times 10^{-3} mol−1^{-1} L s−1^{-1}. Which of the following statements are true?
A. When concentration of 'X' is increased to four times, the rate of reaction becomes 1616 times.
B. The reaction is a second order reaction.
C. The half-life period is independent of the concentration of X.
D. Decomposition of N2O5N_2 O_5 is an example of the above reaction.
E. ln⁡[Ro][R]\ln\dfrac{[R_o]}{[R]} vs time is valid for the above reaction.
Choose the correct answer from the options given below:

Options

  1. AA and B Only
  2. BA, B and C Only
  3. CA, B, D and E Only
  4. DC and D Only

Correct answer

A. A and B Only

Step-by-step solution

The unit of the rate constant kk is mol−1^{-1} L s−1^{-1}.

The general unit of the rate constant for an nn-th order reaction is (mol L−1^{-1})1−n^{1-n} s−1^{-1}.

Equating the powers of the concentration units, we get 1−n=−1⇒n=21-n = -1 \Rightarrow n = 2.

Thus, the reaction is a second-order reaction. Statement B is correct.

For a second-order reaction, Rate =k[X]2= k[X]^2. When the concentration of XX is increased to 44 times, the new rate is k(4[X])2=16k[X]2k(4[X])^2 = 16k[X]^2, which is 1616 times the original rate. Statement A is correct.

The half-life of a second-order reaction is t1/2=1k[X]0t_{1/2} = \dfrac{1}{k[X]_0}, which depends inversely on the initial concentration. Statement C is incorrect.

The decomposition of N2O5N_2O_5 is a well-known first-order reaction. Statement D is incorrect.

The equation ln⁡[Ro][R]=kt\ln\dfrac{[R_o]}{[R]} = kt represents the integrated rate law for a first-order reaction, not a second-order reaction. Statement E is incorrect.

Therefore, only statements A and B are correct.

Answer: A and B Only
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