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JEE Main 20258 AprilEvening Shift
Exam
JEE Main
Year
2025
Date
8 April
Shift
Evening Shift
Subject
Chemistry
Chapter
Chemical Kinetics

JEE Main 2025 · 8 April · Evening Shift · Chemistry · Chemical Kinetics

In a first order decomposition reaction, the time taken for the...

In a first order decomposition reaction, the time taken for the decomposition of reactant to one fourth and one eighth of its initial concentration are t1t_1 and t2(s)t_2(s), respectively. The ratio t1/t2t_1 / t_2 will :

Options

  1. A43\frac{4}{3}
  2. B32\frac{3}{2}
  3. C34\frac{3}{4}
  4. D23\frac{2}{3}

Correct answer

D. 23\frac{2}{3}

Step-by-step solution

For Ist \mathrm{I}^{\text{st }} order reactionWhen Ct=Co/4\mathrm{C}_{\mathrm{t}}=\mathrm{Co} / 4t1=2t50%.& when Ct=Co/8&t2=3t50%& so t1t2=23\begin{aligned}& \mathrm{t}_1=2 \mathrm{t}_{50 \%}. \& \text{ when } \mathrm{C}_{\mathrm{t}}=\mathrm{Co} / 8 \& \mathrm{t}_2=3 \mathrm{t}_{50 \%} \& \text{ so } \frac{\mathrm{t}_1}{\mathrm{t}_2}=\frac{2}{3}\end{aligned}$$
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