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JEE Main 202315 AprilMorning Shift
Exam
JEE Main
Year
2023
Date
15 April
Shift
Morning Shift
Subject
Chemistry
Chapter
Chemical Kinetics

JEE Main 2023 · 15 April · Morning Shift · Chemistry · Chemical Kinetics

For a reversible reaction A ⇌ B , the ∆ H forward reaction = 20kJ...

For a reversible reaction A⇌BA ⇌ B, the ∆H∆ H forward reaction =20kJmol–1= 20kJ{mol}^{– 1}. The activation energy of the uncatalyzed forward reaction is 300kJmol–1300kJ{mol}^{– 1}. When the reaction is catalysed keeping the reactant concentration same, the rate of the catalysed forward reaction at 27∘C{27}^{∘}C is found to be same as that of the uncatalyzed reaction at 327∘C{327}^{∘}C. The activation energy of the catalysed backward reaction is _______kJmol–1kJ{mol}^{– 1}.

Correct answer

0

Step-by-step solution

As per the question

To determine the activation energy of the catalyzed backward reaction, we need to use the Arrhenius equation and the given information.

The Arrhenius equation is given by:

k=Ae(−Ea/RT)k = {Ae}^{( - Ea / RT )}

Ae−300×103600×R=Ae−Ea300×R{Ae}^{- \dfrac{300 \times {10}^{3}}{600 \times R}} = Ae\dfrac{- Ea}{300 \times R}

⇒1032=Ea300⇒ \dfrac{{10}^{3}}{2} = \dfrac{Ea}{300}

⇒Ea=150×103Jmol–1⇒ {E}_{a} = 150 \times {10}^{3}J{mol}^{– 1}

⇒Ea=150kJmol–1⇒ {E}_{a} = 150kJ{mol}^{– 1}

∴∴ Activation energy of catalysed backward reaction

Energy of activation for backward reactionEb=Ea−∆H{E}_{b} = {E}_{a} - ∆ H

=150−20=130kJmol–1= 150 - 20 = 130kJ{mol}^{– 1}

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