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JEE Main 202330 JanuaryEvening Shift
Exam
JEE Main
Year
2023
Date
30 January
Shift
Evening Shift
Subject
Chemistry
Chapter
Chemical Kinetics

JEE Main 2023 · 30 January · Evening Shift · Chemistry · Chemical Kinetics

An organic compound undergoes first order decomposition. If the...

An organic compound undergoes first order decomposition. If the time taken for the 6060 % decomposition is 540s540s, then the time required for 9090 % decomposition will be is _____ s. (Nearest integer).

Given : ln⁡10=2.3;log⁡2=0.3\ln 10 = 2 . 3; \log 2 = 0 . 3

Correct answer

0

Step-by-step solution

For the First order reaction, integrated rate equation can be written as follows,

t=1klna0att=timek=rateconstanta0=intialconcentrationat=concentrationattimett = \dfrac{1}{k}ln\dfrac{{a}_{0}}{{a}_{t}}t = timek = rateconstant{a}_{0} = intialconcentration{a}_{t} = concentrationattimet

t1t2=1klna00.4a01klna00.1a0\dfrac{{t}_{1}}{{t}_{2}} = \dfrac{\dfrac{1}{k}ln\dfrac{{a}_{0}}{0 . 4{a}_{0}}}{\dfrac{1}{k}ln\dfrac{{a}_{0}}{0 . 1{a}_{0}}}

540t2=ln104ln⁡10\dfrac{540}{{t}_{2}} = \dfrac{ln\dfrac{10}{4}}{\ln 10}

540t2=log⁡10−log⁡4log⁡10\dfrac{540}{{t}_{2}} = \dfrac{\log 10 - \log 4}{\log 10}

540t2=1−0.61\dfrac{540}{{t}_{2}} = \dfrac{1 - 0 . 6}{1}

⇒540t2=0.4⇒ \dfrac{540}{{t}_{2}} = 0 . 4

⇒t2=5400.4=1350sec⇒ {t}_{2} = \dfrac{540}{0 . 4} = 1350sec

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