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JEE Main 202227 JuneEvening Shift
Exam
JEE Main
Year
2022
Date
27 June
Shift
Evening Shift
Subject
Chemistry
Chapter
Chemical Kinetics

JEE Main 2022 · 27 June · Evening Shift · Chemistry · Chemical Kinetics

It has been found that for a chemical reaction with rise in...

It has been found that for a chemical reaction with rise in temperature by 9K9K the rate constant gets doubled. Assuming a reaction to be occurring at 300K300K, the value of activation energy is found to be kJmol−1{kJmol}^{- 1}. [nearest integer] (Given ln⁡10=2.3,R=8.3JK−1mol−1,log⁡2=0.30\ln 10 = 2 . 3, R = 8 . 3J{K}^{- 1}{mol}^{- 1}, \log 2 = 0 . 30)

Correct answer

0

Step-by-step solution

Arrhenius equation for the rate constant of a reaction in terms of energy of activation at two different temperatures is given by

log⁡(K2K1)=Ea2.3R[1T1−1T2]\log \left(\dfrac{{K}_{2}}{{K}_{1}}\right) = \dfrac{{E}_{a}}{2 . 3R}\left[\dfrac{1}{{T}_{1}} - \dfrac{1}{{T}_{2}}\right]

Rise in temperature =9K= 9K

Initial temperature =300K= 300K

log⁡(K309K300)=Ea2.3R[1300−1309]\log \left(\dfrac{{K}_{309}}{{K}_{300}}\right) = \dfrac{{E}_{a}}{2 . 3R}\left[\dfrac{1}{300} - \dfrac{1}{309}\right]

log⁡2=Ea2.3R[9300×309]\log 2 = \dfrac{{E}_{a}}{2 . 3R}\left[\dfrac{9}{300 \times 309}\right]

Ea=2.3×0.30×300×3099{E}_{a} = \dfrac{2 . 3 \times 0 . 30 \times 300 \times 309}{9}

Ea=58.988×103J=58.988kJ=59kJ{E}_{a} = 58 . 988 \times {10}^{3}J = 58 . 988kJ = 59kJ

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