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JEE Main 202127 JulyEvening Shift
Exam
JEE Main
Year
2021
Date
27 July
Shift
Evening Shift
Subject
Chemistry
Chapter
Chemical Kinetics

JEE Main 2021 · 27 July · Evening Shift · Chemistry · Chemical Kinetics

For the first order reaction A → 2B, 1 mole of reactant A gives 0 ....

For the first order reaction A \to 2B, 1moleofreactantAgivesmole of reactant A gives0 . 2molesofmoles ofBafterafter100minutes.Thehalflifeofthereactionis......min.(Roundofftothenearestinteger).</p><p>[Useminutes. The half life of the reaction is ...... min. (Round off to the nearest integer).</p><p>[Use: \ln 2 = 0 . 69, \ln 10 = 2 . 3</p><p>Propertiesoflogarithms</p><p>Properties of logarithms: ln{x}^{y} = ylnx</p><p>\leftln(xy)=ln⁡x−ln⁡y]</p><p>\leftln \left(\dfrac{x}{y}\right) = \ln x - \ln y]

(Round off to the nearest integer)

Correct answer

0

Step-by-step solution

A⟶2Bt=01t=100min1−x2xA ⟶ 2Bt = 01t = 100\text{min}1 - x2x

2x=0.2⇒x=0.1[At]=1−x=0.92x = 0 . 2 ⇒ x = 0 . 1 [ {A}_{t} ] = 1 - x = 0 . 9

Now, t=t1/2ln⁡2×⌊A0][At]t = \dfrac{{t}_{1/2}}{\ln 2} \times \dfrac{\left⌊{A}_{0}\right]}{\left[{A}_{t}\right]}

100=t1/2ln⁡2×ln10.9⇒t1/2=655min100 = \dfrac{{t}_{1/2}}{\ln 2} \times ln\dfrac{1}{0 . 9} ⇒ {t}_{1/2} = 655min

(taking ln⁡3=1.11)\ln 3 = 1 . 11 )

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