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JEE Main2012ChemistryChemical KineticsActual

In a chemical reaction A is converted into B . The rates of reaction, starting with initial concentrations of A as 2 10⁻³ M and 1 10⁻³ M , are equal to 2.40 10⁻⁴ Ms ⁻¹ and 0.60 10⁻⁴ Ms ⁻¹ respectively. The order of reaction with respect to reactant A will be

Options

  1. A0
  2. B1.5
  3. C1
  4. D2

Correct answer

D. 2

Step-by-step solution

A B Initial concentration Rate of reaction array ll 2 10⁻³ M & 2.40 10⁻⁴ Ms ⁻¹ 1 10⁻³ M & 0.60 10⁻⁴ Ms ⁻¹ array rate of reaction r=k[A]^x where x= order of reaction hence aligned & 2.40 10⁻⁴=k [2 10⁻³ ]^x & 0.60 10⁻⁴=k [1 10⁻³ ]^x aligned on dividing eqn.(i) from eqn. (ii) we get 4=(2)^x x=2 i.e. order of reaction =2

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