Quantrex Quantrex AcademyJEE · NEET · NDA PYQs with solutions Open app
JEE Main2003ChemistryChemical KineticsActual

For the reaction system: 2 NO ( g )+ O ₂( ~g ) 2 NO ₂( ~g ) volume is suddenly reduce to half its value by increasing the pressure on it. If the reaction is of first order with respect to O ₂ and second order with respect to NO , the rate of reaction will

Options

  1. Adiminish to one-eighth of its initial value
  2. Bincrease to eight times of its initial value
  3. Cincrease to four times of its initial value
  4. Ddiminish to one-fourth of its initial value

Correct answer

B. increase to eight times of its initial value

Step-by-step solution

r = k [ O ₂ ][ NO ]^2 . When the volume is reduced to 1 / 2 , The conc. will double. New rate = k [2 O ₂ ][2 NO ]^2=8 k [ O ^2 ][ NO ]^2 . The new rate increases by eight times.

Practice Chemical Kinetics on Quantrex Academy →

More from Chemical Kinetics

For a reversible reaction R P , at constant temperature, both the forward and the backward reactions are first order elementary reactions with rate constants k_f and k_b , respecti 2026For a first-order reaction R P at a given temperature, k is the rate constant. For this reaction, at the given temperature, the concentrations of R and P at a time t are [ R ] and 2026Given below are two statements: R=8.314 J K ⁻¹ mol ⁻¹ and 1 cal =4.2 J Statement I: When E_a=12.6 kcal/mol, the room temperature rate constant is doubled by a 10 ,^ C increase in t 2026Decomposition of a hydrocarbon follows the equation k = (5.5 10¹¹ , s ⁻¹) ,e^ -28000 , K T . The activation energy of reaction is __________ kJ mol ⁻¹ . (Nearest Integer) Given : R 2026For a reaction A P at T K , the half life (t_ 1/2 ) is plotted as a function of initial concentration [A]₀ of A as given below. The value of x in the given figure is _______ s (Nea 2026First order gas phase reaction A B + C p_i = initial pressure of gas A, p_t = total pressure of the reaction mixture at time t Expression of rate constant ( k ) is 2026If the half life of a first order reaction is 6.93 minutes then the time required for completion of 99 % of the reaction will be _____ minutes. (Given : 2 = 0.3010 ) 2026Consider the given graph showing variation of reactant concentration with time. Three different reactions were started with identical initial concentration of reactants. Which of t 2026 Full Chemical Kinetics list All JEE Main PYQs