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JEE Main 20266 AprilMorning Shift
Exam
JEE Main
Year
2026
Date
6 April
Shift
Morning Shift
Subject
Chemistry
Chapter
Classification of Elements and Periodicity in Properties

JEE Main 2026 · 6 April · Morning Shift · Chemistry · Classification of Elements and Periodicity in Properties

Given below are two statements: Statement I: Aluminium is more...

Given below are two statements:

Statement I: Aluminium is more electropositive than thallium as the standard electrode potential value of EAl3+/Al∘E^{\circ}_{\text{Al}^{3+}/\text{Al}} is negative and ETl3+/Tl∘E^{\circ}_{\text{Tl}^{3+}/\text{Tl}} is positive.

Statement II: The sum of first three ionization enthalpies of boron is very high when compared to that of aluminium. Due to this reason boron forms covalent compounds only and aluminium forms Al3+\text{Al}^{3+} ion.

In the light of the above statements, choose the correct answer from the options given below

Options

  1. ABoth Statement I and Statement II are true
  2. BBoth Statement I and Statement II are false
  3. CStatement I is true but Statement II is false
  4. DStatement I is false but Statement II is true

Correct answer

A. Both Statement I and Statement II are true

Step-by-step solution

Statement I: The standard reduction potential EAl3+/Al∘E^{\circ}_{\text{Al}^{3+}/\text{Al}} is −1.66-1.66 V, which is highly negative, indicating that aluminium has a strong tendency to lose electrons and is highly electropositive. The standard reduction potential ETl3+/Tl∘E^{\circ}_{\text{Tl}^{3+}/\text{Tl}} is +1.26+1.26 V, which is positive, indicating that thallium is less electropositive than aluminium. Thus, Statement I is true.

Statement II: Boron has a very small atomic size, resulting in a very high sum of its first three ionization enthalpies. This high energy requirement prevents boron from losing three electrons to form B3+\text{B}^{3+} ions, so it forms only covalent compounds. In contrast, aluminium has a larger size and a significantly lower sum of its first three ionization enthalpies, allowing it to easily form Al3+\text{Al}^{3+} ions in its compounds. Thus, Statement II is true.

Both Statement I and Statement II are true.

Answer: Both Statement I and Statement II are true
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