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JEE Main 20264 AprilEvening Shift
Exam
JEE Main
Year
2026
Date
4 April
Shift
Evening Shift
Subject
Chemistry
Chapter
Classification of Elements and Periodicity in Properties

JEE Main 2026 · 4 April · Evening Shift · Chemistry · Classification of Elements and Periodicity in Properties

The electronegativity of a group 13 element 'E' is same as that of...

The electronegativity of a group 13 element 'E' is same as that of Ge (on Pauling scale and upto one decimal point). The CORRECT statements about E3+E^{3+} are
A. It can act as a reducing agent.
B. It can act as an oxidizing agent.
C. E3+E^{3+} is more stable than E+E^+.
D. The standard electrode potential value for E3+/EE^{3+}/E is positive.
Choose the correct answer from the options given below:

Options

  1. AA and C Only
  2. BB and C Only
  3. CB and D Only
  4. DA and D Only

Correct answer

C. B and D Only

Step-by-step solution

The electronegativity of Ge on the Pauling scale is 1.81.8. In Group 13, the electronegativity values are B (2.02.0), Al (1.51.5), Ga (1.61.6), In (1.71.7), and Tl (1.81.8). Thus, the element 'E' is Thallium (Tl).

Due to the inert pair effect, the +1+1 oxidation state is much more stable than the +3+3 oxidation state for the heavier elements of Group 13, especially Thallium. Therefore, Tl+Tl^+ is more stable than Tl3+Tl^{3+}. This makes statement C incorrect.

Since Tl3+Tl^{3+} is relatively unstable, it readily accepts two electrons to form the more stable Tl+Tl^+ ion (Tl3++2e−→Tl+Tl^{3+} + 2e^- \rightarrow Tl^+). Because it undergoes reduction easily, Tl3+Tl^{3+} acts as a strong oxidizing agent. This makes statement A incorrect and statement B correct.

The standard electrode potential for the reduction of Tl3+Tl^{3+} to Tl (ETl3+/Tl∘E^{\circ}_{Tl^{3+}/Tl}) is +1.26 V+1.26\text{ V}, which is a positive value. This makes statement D correct.

Therefore, only statements B and D are correct.
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