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JEE Main 20264 AprilEvening Shift
Exam
JEE Main
Year
2026
Date
4 April
Shift
Evening Shift
Subject
Chemistry
Chapter
d and f Block Elements

JEE Main 2026 · 4 April · Evening Shift · Chemistry · d and f Block Elements

Consider |x| is the difference in oxidation states of Mn in highest...

Consider ∣x∣|x| is the difference in oxidation states of Mn in highest manganese fluoride and highest manganese oxide. The ions with ∣x∣|x| number of unpaired electrons from the following are:
A. Sc3+Sc^{3+}
B. Zn2+Zn^{2+}
C. V2+V^{2+}
D. Fe2+Fe^{2+}
E. Co2+Co^{2+}
Choose the correct answer from the options given below:

Options

  1. AA and B Only
  2. BC, D and E Only
  3. CC and E Only
  4. DB and E Only

Correct answer

C. C and E Only

Step-by-step solution

The highest manganese fluoride is MnF4MnF_4, where the oxidation state of Mn is +4+4.

The highest manganese oxide is Mn2O7Mn_2O_7, where the oxidation state of Mn is +7+7.

The difference in oxidation states is ∣x∣=∣7−4∣=3|x| = |7 - 4| = 3.

The number of unpaired electrons in the given ions are:
Sc3+Sc^{3+}: [Ar]3d0⇒0[Ar] 3d^0 \Rightarrow 0 unpaired electrons
Zn2+Zn^{2+}: [Ar]3d10⇒0[Ar] 3d^{10} \Rightarrow 0 unpaired electrons
V2+V^{2+}: [Ar]3d3⇒3[Ar] 3d^3 \Rightarrow 3 unpaired electrons
Fe2+Fe^{2+}: [Ar]3d6⇒4[Ar] 3d^6 \Rightarrow 4 unpaired electrons
Co2+Co^{2+}: [Ar]3d7⇒3[Ar] 3d^7 \Rightarrow 3 unpaired electrons

Thus, V2+V^{2+} (C)andCo2+and Co^{2+} (E) have 33 unpaired electrons.

Answer: C and E Only
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