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JEE Main 202628 JanuaryMorning Shift
Exam
JEE Main
Year
2026
Date
28 January
Shift
Morning Shift
Subject
Chemistry
Chapter
d and f Block Elements

JEE Main 2026 · 28 January · Morning Shift · Chemistry · d and f Block Elements

Given below are two statements: Statement I : The number of pairs,...

Given below are two statements:
Statement I: The number of pairs, from the following, in which both the ions are coloured in aqueous solution is 3. [Sc3+,Ti3+],[Mn2+,Cr2+],\left[\mathrm{Sc}^{3+}, \mathrm{Ti}^{3+}\right],\left[\mathrm{Mn}^{2+}, \mathrm{Cr}^{2+}\right],\left[\mathrm{Cu}^{2+}, \mathrm{Zn}^{2+}\right]and[Ni2+,Ti4+]and \left[\mathrm{Ni}^{2+}, \mathrm{Ti}^{4+}\right]
Statement II: Th4+\mathrm{Th}^{4+} is the strongest reducing agent among Th4+,Ce4+,Gd3+\mathrm{Th}^{4+}, \mathrm{Ce}^{4+}, \mathrm{Gd}^{3+} and Eu2+\mathrm{Eu}^{2+}.
In the light of the above statements, choose the correct answer from the options given below

Options

  1. ABoth Statement I and Statement II are false
  2. BBoth Statement I and Statement II are true
  3. CStatement I is false but Statement II is true
  4. DStatement I is true but Statement II is false

Correct answer

A. Both Statement I and Statement II are false

Step-by-step solution

[Sc³⁺, Ti³⁺] has Sc³⁺ colorless (no d-electrons) and Ti³⁺ colored;
[Mn²⁺, Cr²⁺] has Mn²⁺ colorless (d⁵ half-filled, no d-d transitions) and Cr²⁺ colored;
[Cu²⁺, Zn²⁺] has Cu²⁺ colored and Zn²⁺ colorless (d¹⁰ filled);
[Ni²⁺, Ti⁴⁺] has Ni²⁺ colored and Ti⁴⁺ colorless (no d-electrons).
Zero pairs have both ions colored. Statement I is FALSE.

Th⁴⁺ is not a reducing agent. Statement II is FALSE.

Both statements are false.
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