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JEE Main202623 January 2026Evening ShiftChemistryd and f Block ElementsActual

The oxidation state of chromium in the final product formed in the reaction between KI and acidified K ₂ Cr ₂ O ₇ solution is:

Options

  1. A+6
  2. B+3
  3. C+4
  4. D+2

Correct answer

B. +3

Step-by-step solution

In the reaction between KI and acidified K₂Cr₂O₇ , Cr in the dichromate ion exists in +6 oxidation state. Iodide ions are oxidized to I₂ while chromium is reduced. The reduction product is Cr³⁺ ions, which form chromium(III) salts like Cr₂(SO₄)₃ or coordination complexes. Therefore, the oxidation state of chromium in the final product is +3.

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