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JEE Main 20254 AprilMorning Shift
Exam
JEE Main
Year
2025
Date
4 April
Shift
Morning Shift
Subject
Chemistry
Chapter
d and f Block Elements

JEE Main 2025 · 4 April · Morning Shift · Chemistry · d and f Block Elements

KMnO_4 acts as an oxidising agent in acidic medium. ' X ' is the...

KMnO4\mathrm{KMnO}_4 acts as an oxidising agent in acidic medium. ' X ' is the difference between the oxidation states of Mn in reactant and product. ' Y ' is the number of ' d ' electrons present in the brown red precipitate formed at the end of the acetate ion test with neutral ferric chloride. The value of X+Y\mathrm{X}+\mathrm{Y} is ______.

Correct answer

0

Step-by-step solution

\underset{(\mathrm{O}. \mathrm{A})}{\stackrel{+7}{\mathrm{KMnO}}} \xrightarrow{\text{ Acidic medium }} \mathrm{Mn}^{2+}<br/>Xisdifferenceinoxidationstate.<br/><br />X is difference in oxidation state.<br />6 \mathrm{CH}_3 \mathrm{COO}^{\ominus}+\mathrm{Fe}^{3+}+\mathrm{H}_2 \mathrm{O} \rightarrow\left[\mathrm{Fe}_3\left(\mathrm{OH}_2\right)\left(\mathrm{CH}_3 \mathrm{COO}\right)_6\right]^{\oplus}+2 \mathrm{H}^{\oplus}<br/>[Fe3(OH)2(CH3COO)6]⊕(Brown red ppt)+4H2O→[Fe(OH)2(CH3COO]+CH3COOH+H⊕<br/>Fe3+<br />\left[\mathrm{Fe}_3(\mathrm{OH})_2\left(\mathrm{CH}_3 \mathrm{COO}\right)_6\right]^{\oplus} \text{(Brown red ppt)} +4 \mathrm{H}_2 \mathrm{O}\rightarrow\left[\mathrm{Fe}(\mathrm{OH})_2\left(\mathrm{CH}_3 \mathrm{COO}\right]+\mathrm{CH}_3 \mathrm{COOH}+\mathrm{H}^{\oplus}\right.<br />\mathrm{Fe}^{3+}\Rightarrow 3  d54 s0\mathrm{~d}^5 4 \mathrm{~s}^0contains 5 d electrons
So Y=5Y=5
X+Y=5+5=10X+Y=5+5=10
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