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JEE Main 20244 AprilEvening Shift
Exam
JEE Main
Year
2024
Date
4 April
Shift
Evening Shift
Subject
Chemistry
Chapter
d and f Block Elements

JEE Main 2024 · 4 April · Evening Shift · Chemistry · d and f Block Elements

A first row transition metal with highest enthalpy of atomisation,...

A first row transition metal with highest enthalpy of atomisation, upon reaction with oxygen at high temperature forms oxides of formula (\mathrm{M}}_{2} \mathrm{O}_{\mathrm{n}}) (where (\mathrm{n}=3,4), 5). The 'spin-only' magnetic moment value of the amphoteric oxide from the above oxides is ______ (\mathrm{BM})(nearinteger)(Givenatomicnumber:(Sc) (near integer) (Given atomic number: (\mathrm{Sc}: 21, Ti\mathrm{Ti}: 22, \mathrm{ V}: 23, Cr\mathrm{Cr}: 24, Mn\mathrm{Mn}: 25, Fe\mathrm{Fe}: 26, Co\mathrm{Co}: 27), (\mathrm{Ni}:28,Cu: 28, \mathrm{Cu}: 29, Zn\mathrm{Zn}: 30))

Correct answer

0

Step-by-step solution

'V\mathrm{V}' has highest enthalpy of atomisation ( 515 kJ/mol515 \mathrm{~kJ} / \mathrm{mol} ) among first row transition elements. V2O5\mathrm{V}_2 \mathrm{O}_5
Here ' V\mathrm{V} ' is in +5 oxidation state V+5⇒1 s22 s22p63 s23p6 (no unpaired electrons) \mathrm{V}^{+5} \Rightarrow 1 \mathrm{~s}^2 2 \mathrm{~s}^2 2 \mathrm{p}^6 3 \mathrm{~s}^2 3 \mathrm{p}^6 \text{ (no unpaired electrons) }
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