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JEE Main 202311 AprilMorning Shift
Exam
JEE Main
Year
2023
Date
11 April
Shift
Morning Shift
Subject
Chemistry
Chapter
d and f Block Elements

JEE Main 2023 · 11 April · Morning Shift · Chemistry · d and f Block Elements

When a solution of mixture having two inorganic salts was treated...

When a solution of mixture having two inorganic salts was treated with freshly prepared ferrous sulphate in acidic medium, a dark brown ring was formed whereas on treatment with neutral FeCl3{FeCl}_{3}, it gave deep red colour which disappeared on boiling and a brown red ppt was formed. The mixture contains

Options

  1. ASO32− and CH3COO−{SO}_{3}^{2 -} \text{ and } {CH}_{3}{COO}^{-}
  2. BCH3COO− and NO3−{CH}_{3}{COO}^{-} \text{ and } {NO}_{3}^{-}
  3. CSO32− and C2O42−{SO}_{3}^{2 -} \text{ and } {C}_{2}{O}_{4}^{2 -}
  4. DC2O42− and NO3−{C}_{2}{O}_{4}^{2 -} \text{ and } {NO}_{3}^{-}

Correct answer

B. CH3COO− and NO3−{CH}_{3}{COO}^{-} \text{ and } {NO}_{3}^{-}

Step-by-step solution

The brown ring test is a typical nitrate test that involves adding iron(II) sulphate to a nitrate solution, then slowly adding strong sulfuric acid until the acid forms a layer below the aqueous solution. The existence of the nitrate ion will be shown by the formation of a brown ring at the junction of the two layers. Dark brown ring is formed in the confirmatory test of NO3−{NO}_{3}^{-} − ions. Deep red precipitate with FeCl3{FeCl}_{3} is formed in the presence of CH3COO−{CH}_{3}{COO}^{-} ions.
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