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JEE Main202311 Apr 2023Morning ShiftChemistryd and f Block ElementsActual

When a solution of mixture having two inorganic salts was treated with freshly prepared ferrous sulphate in acidic medium, a dark brown ring was formed whereas on treatment with neutral FeCl 3 , it gave deep red colour which disappeared on boiling and a brown red ppt was formed. The mixture contains

Options

  1. ASO 3 2 - & CH 3 COO -
  2. BCH 3 COO - & NO 3 -
  3. CSO 3 2 - & C 2 O 4 2 -
  4. DC 2 O 4 2 - & NO 3 -

Correct answer

B. CH 3 COO - & NO 3 -

Step-by-step solution

The brown ring test is a typical nitrate test that involves adding iron(II) sulphate to a nitrate solution, then slowly adding strong sulfuric acid until the acid forms a layer below the aqueous solution. The existence of the nitrate ion will be shown by the formation of a brown ring at the junction of the two layers. Dark brown ring is formed in the confirmatory test of NO 3 - − ions. Deep red precipitate with FeCl 3 is formed in the presence of CH 3 COO - ions.

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