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JEE Main 202325 JanuaryMorning Shift
Exam
JEE Main
Year
2023
Date
25 January
Shift
Morning Shift
Subject
Chemistry
Chapter
d and f Block Elements

JEE Main 2023 · 25 January · Morning Shift · Chemistry · d and f Block Elements

Match the List-I with List-II : Cations Group reaction P → Pb ^ 2 +...

Match the List-I with List-II :

Cations Group reaction
P→Pb2+,Cu2+P \to {Pb}^{2 +}, {Cu}^{2 +} H2S{H}_{2}S gas in presence of dilute HClHCl
Q→Al3+,Fe3+Q \to {Al}^{3 +}, {Fe}^{3 +} ( NH 4){\left({\text{ NH }}_{4}\right)}_{2}{CO}_{3}inpresenceofin presence of{NH}_{4}OH</td></tr><tr><td></td> </tr> <tr> <td>R \to {Co}^{2 +}, {Ni}^{2 +}</td><td></td> <td>{NH}_{4}OHinpresenceofin presence of{NH}_{4}CI</td></tr><tr><td></td> </tr> <tr> <td>S \to {Ba}^{2 +}, {Ca}^{2 +}</td><td></td> <td>{H}_{2}Sinpresenceofin presence of{NH}_{4}OH

Options

  1. AP→i,Q→iii,R→ii,S→ivP \to i, Q \to iii, R \to ii, S \to iv
  2. BP→iv,Q→ii,R→iii,S→iP \to iv, Q \to ii, R \to iii, S \to i
  3. CP→iii,Q→i,R→iv,S→iiP \to iii, Q \to i, R \to iv, S \to ii
  4. DP→i,Q→iii,R→iv,S→iiP \to i, Q \to iii, R \to iv, S \to ii

Correct answer

D. P→i,Q→iii,R→iv,S→iiP \to i, Q \to iii, R \to iv, S \to ii

Step-by-step solution

Group reagents for precipitating ions:

Group Cations Group reagent
Zero NH4+{NH}_{4}^{+} None
I Pb2+{Pb}^{2 +} Dilute HCl
II Pb2+,Cu2+,As3+{Pb}^{2 +}, {Cu}^{2 +}, {As}^{3 +} H2S{H}_{2}S gas in presence of dil. HCl
III Al3+,Fe3+{Al}^{3 +}, {Fe}^{3 +} NH4OH{NH}_{4}OH in presence of NH4Cl{NH}_{4}Cl
IV Co2+,Ni2+,Mn2+,Zn2+{Co}^{2 +}, {Ni}^{2 +}, {Mn}^{2 +}, {Zn}^{2 +} H2S{H}_{2}S in presence of NH4OH{NH}_{4}OH
V Ba2+,Sr2+,Ca2+{Ba}^{2 +}, {Sr}^{2 +}, {Ca}^{2 +} (NH4)2CO3( {NH}_{4}{)}_{2}{CO}_{3} in presence of NH4OH{NH}_{4}OH
VI Mg2+{Mg}^{2 +} None

So, the correct answer is P→i,Q→iii,R→iv,S→iiP \to i, Q \to iii, R \to iv, S \to ii

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