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JEE Main 202227 JulyEvening Shift
Exam
JEE Main
Year
2022
Date
27 July
Shift
Evening Shift
Subject
Chemistry
Chapter
d and f Block Elements

JEE Main 2022 · 27 July · Evening Shift · Chemistry · d and f Block Elements

The oxidation state of manganese in the product obtained in a...

The oxidation state of manganese in the product obtained in a reaction of potassium permanganate and hydrogen peroxide in basic medium is

Correct answer

4

Step-by-step solution

This KMnO4{KMnO}_{4} is a powerful oxidizing agent in neutral, acidic, and alkaline medium. The H2O2{H}_{2}{O}_{2} is also an oxidizing agent but in the reaction of KMnO4{KMnO}_{4} with the H2O2{H}_{2}{O}_{2}. The H2O2{H}_{2}{O}_{2}loses its electron and acts as a reducing agent. In an acidic medium, theMnO4−{MnO}_{4}^{-} ions involve the addition of 5 electrons and the two peroxide ions give out two electrons. In dilute alkaline medium or in neutral medium MnO4−{MnO}_{4}^{-} ions involve the addition of 3 electrons. The reaction in basic medium is given below.

2KMnO4+3H2O2⟶basicmedium2MnO2+4+3O2+2H2O+2KOH2{KMnO}_{4} + 3{H}_{2}{O}_{2}\overset{basicmedium}{⟶}\overset{+ 4}{2{MnO}_{2}} + 3{O}_{2} + 2{H}_{2}O + 2KOH

The oxidation state of MninMnO2Mn\text{in}{MnO}_{2} is +4.+ 4 .

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