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JEE Main 202227 JulyMorning Shift
Exam
JEE Main
Year
2022
Date
27 July
Shift
Morning Shift
Subject
Chemistry
Chapter
d and f Block Elements

JEE Main 2022 · 27 July · Morning Shift · Chemistry · d and f Block Elements

In the titration of KMnO _ 4 and oxalic acid in acidic medium, the...

In the titration of KMnO4{KMnO}_{4} and oxalic acid in acidic medium, the change in oxidation number of carbon at the end point is

Correct answer

1

Step-by-step solution

The balanced equation of potassium permanganate and oxalic acid reaction in acidic medium is shown below.

2KMn+7O4+5H2C2+3O4+3H2SO4(dil.)→K2SO4+2M+2nSO4+10C+4O2+8H2O2K\overset{+ 7}{Mn}{O}_{4} + 5{H}_{2}\overset{+ 3}{{C}_{2}}{O}_{4} + 3{H}_{2}{SO}_{4}\left(dil .\right) \to {K}_{2}{SO}_{4} + 2\overset{+ 2}{M}{nSO}_{4} + 10\overset{+ 4}{C}{O}_{2} + 8{H}_{2}O

The initial oxidation state of carbon in the oxalic acid is +3+ 3. The oxidation state of carbon at the end point is +4+ 4(in carbon dioxide). Hence, the change in oxidation state of carbon at the end point is 1.

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