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JEE Main 202226 JulyMorning Shift
Exam
JEE Main
Year
2022
Date
26 July
Shift
Morning Shift
Subject
Chemistry
Chapter
d and f Block Elements

JEE Main 2022 · 26 July · Morning Shift · Chemistry · d and f Block Elements

The dark purple colour of KMnO _ 4 disappears in the titration with...

The dark purple colour of KMnO4{KMnO}_{4} disappears in the titration with oxalic acid in acidic medium. The overall change in the oxidation number of manganese in the reaction is

Options

  1. A55
  2. B11
  3. C77
  4. D22

Correct answer

A. 55

Step-by-step solution

The overall reaction takes place in the process is

2KMnO4+3H2SO4+5(COOH)2→K2SO4+2MnSO4+8H2O+10CO2↑2{KMnO}_{4} + 3{H}_{2}{SO}_{4} + 5{\left(COOH\right)}_{2} \to {K}_{2}{SO}_{4} + 2{MnSO}_{4} + 8{H}_{2}O + 10{CO}_{2} ↑

Potassium permanganate is a strong oxidising agent and in the presence of sulfuric acid it acts as a powerful oxidising agent. In acidic medium the oxidising ability of KMnO4{KMnO}_{4} is represented by the following equation.

MnO4−+8H++5e−→Mn2++4H2O{{MnO}_{4}}^{-} + 8{H}^{+} + 5{e}^{-} \to {Mn}^{2 +} + 4{H}_{2}O

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