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JEE Main 202228 JuneMorning Shift
Exam
JEE Main
Year
2022
Date
28 June
Shift
Morning Shift
Subject
Chemistry
Chapter
d and f Block Elements

JEE Main 2022 · 28 June · Morning Shift · Chemistry · d and f Block Elements

Which one of the lanthanoids given below is the most stable in...

Which one of the lanthanoids given below is the most stable in divalent form?

Options

  1. AYbYb (Atomic Number 7070)
  2. BSmSm (Atomic Number 6262)
  3. CEuEu (Atomic Number 6363)
  4. DCeCe (Atomic Number 5858)

Correct answer

C. EuEu (Atomic Number 6363)

Step-by-step solution

Ce+2:(xe)4f2{Ce}^{+ 2}: \left(xe\right)4{f}^{2}

Eu+2:(xe)4f7{Eu}^{+ 2}: \left(xe\right)4{f}^{7}

Sm+2:(xe)4f6{Sm}^{+ 2}: \left(xe\right)4{f}^{6}

Yb+2:(xe)4f14{Yb}^{+ 2}: \left(xe\right)4{f}^{14}

As Yb+2andEu+2{Yb}^{+ 2}and{Eu}^{+ 2} has completely filled and half filled 4f4f orbital, so they would be the most stable. But among the these two Eu+2{Eu}^{+ 2} is more stable based on reduction potential value.

EM3+/M2+°⇒{E}_{{M}^{3 +} / {M}^{2 +}}^{°} ⇒\begin{cases}Eu & Yb \\ - 0 . 35 & - 1 . 05\end{cases}$</p><p>Hence,duetomorereductionpotentialin</p><p>Hence, due to more reduction potential inEuascomparedtoas compared toYb,itcanconcludedthat, it can concluded that{Eu}^{2 +}ismorestablethanis more stable than{Yb}^{2 +}$.

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