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JEE Main 202227 JuneMorning Shift
Exam
JEE Main
Year
2022
Date
27 June
Shift
Morning Shift
Subject
Chemistry
Chapter
d and f Block Elements

JEE Main 2022 · 27 June · Morning Shift · Chemistry · d and f Block Elements

Acidified potassium permanganate solution oxidises oxalic acid. The...

Acidified potassium permanganate solution oxidises oxalic acid. The spin-only magnetic moment of the mangenese product formed from the above reaction is B.M.___(Nearest Integer)

Correct answer

0

Step-by-step solution

2KMnO4+5H2C2O4+3H2SO4→K2SO4+2MnSO4+10CO2+8H2O2{KMnO}_{4} + 5{H}_{2}{C}_{2}{O}_{4} + 3{H}_{2}{SO}_{4} \to {K}_{2}{SO}_{4} + 2{MnSO}_{4} + 10{CO}_{2} + 8{H}_{2}O

In acidic medium, Mn7+{Mn}^{7 +} gets reduced to Mn2+{Mn}^{2 +}

Mn (II) =[Ar]3d5= \left[Ar\right]3{d}^{5}

Number of unpaired electron in Mn2+=5{Mn}^{2 +} = 5

μ=n(n+2)B.M\mu = \sqrt{n\left(n + 2\right)}B . M

μ=5(5+2)B.M\mu = \sqrt{5\left(5 + 2\right)}B . M

μ=5.9B.M\mu = 5 . 9B . M

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