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JEE Main 202125 FebruaryMorning Shift
Exam
JEE Main
Year
2021
Date
25 February
Shift
Morning Shift
Subject
Chemistry
Chapter
d and f Block Elements

JEE Main 2021 · 25 February · Morning Shift · Chemistry · d and f Block Elements

Given below are two statements: Statement I : CeO _ 2 can be used...

Given below are two statements:

Statement I : CeO2{CeO}_{2} can be used for oxidation of aldehydes and ketones.

Statement II : Aqueous solution of EuSO4{EuSO}_{4} is a strong reducing agent. In the light of the above statements, choose the correct answer from the options given below:

Options

  1. ABoth Statement I and Statement II are true
  2. BStatement I is true but Statement II is false
  3. CBoth Statement I and Statement II are false
  4. DStatement I is false but Statement II is true

Correct answer

A. Both Statement I and Statement II are true

Step-by-step solution

The +3+ 3 oxidation state of lanthanide is most stable and therefore lanthanide in +4+ 4 oxidation state has strong tendency to gain e−{e}^{-} and converted into +3+ 3 and therefore act as strong oxidizing agent. e.g.Ce+4e . g . {Ce}^{+ 4} And therefore CeO2{CeO}_{2} is used to oxidized alcohol aldehyde and ketones. Lanthanide in +2+ 2 oxidation state has strong tendency to loss e−{e}^{-} and converted into +3+ 3 oxidation state therefore act as strong reducing agent. ∴EuSO4∴ {EuSO}_{4} act as strong reducing agent.
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