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JEE Main 20198 AprilMorning Shift
Exam
JEE Main
Year
2019
Date
8 April
Shift
Morning Shift
Subject
Chemistry
Chapter
d and f Block Elements

JEE Main 2019 · 8 April · Morning Shift · Chemistry · d and f Block Elements

The lanthanide ion that would show colour is:

The lanthanide ion that would show colour is:

Options

  1. ALu3+L{u}^{3 +}
  2. BLa3+L{a}^{3 +}
  3. CGd3+G{d}^{3 +}
  4. DSm3+S{m}^{3 +}

Correct answer

D. Sm3+S{m}^{3 +}

Step-by-step solution

The elements or ions having unpaired electrons show colour. The valence shell electronic configuration of La3+{La}^{3 +} and Lu3+{Lu}^{3 +} are 4f0and4f144{f}^{0}\text{and}4{f}^{14} respectively. Hence, they are colourless. Gd3+{Gd}^{3 +} is also colourless, this is because, here 4f4f orbitals are half filled,hence stable.As such f−ff - f transitions are not possible because they will destroy the symmetry of 4f4f and make them unstable. Sm3+{Sm}^{3 +} has the valence shell electronic configuration 4f54{f}^{5}, hence, it is coloured due to the presence of unpaired electrons.

La+3=L{a}^{+ 3} = Colourless
Gd+3=G{d}^{+ 3} = Colourless
Sm+3=S{m}^{+ 3} = Pale yellow colour
Lu+3=L{u}^{+ 3} = Colourless

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