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JEE Main 202430 JanuaryEvening Shift
Exam
JEE Main
Year
2024
Date
30 January
Shift
Evening Shift
Subject
Chemistry
Chapter
Electrochemistry

JEE Main 2024 · 30 January · Evening Shift · Chemistry · Electrochemistry

Reduction potential of ions are given below: ClO _ 4 ^ - IO _ 4 ^ -...

Reduction potential of ions are given below:

ClO4−IO4−BrO4−{ClO}_{4}^{-}{IO}_{4}^{-}{BrO}_{4}^{-}

E°=1.19V;E°=1.65V;E°=1.74VE ° = 1 . 19V; E ° = 1 . 65V; E ° = 1 . 74V

The correct order of their oxidising power is:

Options

  1. AClO4−>IO4−>BrO4−{ClO}_{4}^{-} > {IO}_{4}^{-} > {BrO}_{4}^{-}
  2. BBrO4−>IO4−>ClO4−{BrO}_{4}^{-} > {IO}_{4}^{-} > {ClO}_{4}^{-}
  3. CBrO4−>ClO4−>IO4−{BrO}_{4}^{-} > {ClO}_{4}^{-} > {IO}_{4}^{-}
  4. DIO4−>BrO4−>ClO4−{IO}_{4}^{-} > {BrO}_{4}^{-} > {ClO}_{4}^{-}

Correct answer

B. BrO4−>IO4−>ClO4−{BrO}_{4}^{-} > {IO}_{4}^{-} > {ClO}_{4}^{-}

Step-by-step solution

The reduction potential of the substance is the ability of the substance to be reduced. So as the reduction potential increases, the reducing ability of the substance increases. It means the oxidising power of the substance (The ability of the substance to make the other substance to lose the electrons increases, which nothing but oxidising power) increases.

So the decreasing order of oxidising power is BrO4−>IO4−>ClO4−{BrO}_{4}^{-} > {IO}_{4}^{-} > {ClO}_{4}^{-}.

Hence option B is correct.

 

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