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JEE Main 202229 JuneMorning Shift
Exam
JEE Main
Year
2022
Date
29 June
Shift
Morning Shift
Subject
Chemistry
Chapter
Electrochemistry

JEE Main 2022 · 29 June · Morning Shift · Chemistry · Electrochemistry

A dilute solution of sulphuric acid is electrolysed using a current...

A dilute solution of sulphuric acid is electrolysed using a current of 0.10A0 . 10A for 22 hours to produce hydrogen and oxygen gas. The total volume of gases produced at STPSTP is cm3{cm}^{3}. (Nearest integer) [Given : Faraday constant F=96500Cmol−1F = 96500{Cmol}^{- 1} at STPSTP, molar volume of an ideal gas is 22.7Lmol−122 . 7L{mol}^{- 1}]

Correct answer

0

Step-by-step solution

At anode

2H2O→O2(g)+4H++4e−2{H}_{2}O \to {O}_{2}\left(g\right) + 4{H}^{+} + 4{e}^{-}

At cathode

2H++2e−→H2(g)2{H}^{+} + 2{e}^{-} \to {H}_{2}\left(g\right)

Now number of gm eq. =i×t96500= \dfrac{i \times t}{96500}

=0.1×2×60×6096500= \dfrac{0 . 1 \times 2 \times 60 \times 60}{96500}

=0.00746= 0 . 00746

VO2=0.007464×22.7=0.0423{V}_{{O}_{2}} = \dfrac{0 . 00746}{4} \times 22 . 7 = 0 . 0423

VH2=0.007462×22.7=0.0846{V}_{{H}_{2}} = \dfrac{0 . 00746}{2} \times 22 . 7 = 0 . 0846

VTotal≈127ml{V}_{Total} \approx 127ml or cccc

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