JEE Main 20178 AprilOnline
- Exam
- JEE Main
- Year
- 2017
- Date
- 8 April
- Mode
- Online
- Subject
- Chemistry
- Chapter
- Electrochemistry
JEE Main 2017 · 8 April · Online · Chemistry · Electrochemistry
What is the standard reduction potential ( E ^ o ) for Fe ^ 3 + →...
What is the standard reduction potential for {Fe}^{2 +} + 2{e}^{-} \to Fe; {E}_{{Fe}^{2 +} / Fe}^{o} = - 0 .47 V{Fe}^{3 +} + {e}^{-} \to {Fe}^{2 +}; {E}_{{Fe}^{3 +} / {Fe}^{2 +}}^{o} = + 0 .77 V
Options
- A
- B
- C
- D
Correct answer
A.
Step-by-step solution
;
factor
\left(ii\right){Fe}^{3 +} + {e}^{-} \to {Fe}^{2 +}$;
factor
\left(iii\right){Fe}^{2 +} + 2{e}^{-} \to Fe{E}_{3}^{o} = - 0 . 47' n '= 2∆ {G}_{3}^{∘} = - 2 \times F \times - 0 . 47{\Delta G}_{1} = {\Delta G}_{2} + {\Delta G}_{3}- 3{FE}_{{}^{1}}^{o} = \left(- 1 \times 0 .77 \times F\right) + \left(2 \times 0 .47 \times F\right){\text{-E}}_{{}^{1}}^{o} = \dfrac{\left[\left(2 \times 0 .47\right) + \left(- 0 .77\right)\right]F}{3F} = 0 .057 V{\text{E}}_{{}^{1}}^{o} = - 0 .057 V$