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JEE Main 20262 AprilEvening Shift
Exam
JEE Main
Year
2026
Date
2 April
Shift
Evening Shift
Subject
Chemistry
Chapter
General Organic Chemistry

JEE Main 2026 · 2 April · Evening Shift · Chemistry · General Organic Chemistry

Complete combustion of X g of an organic compound gave 0.25 g of...

Complete combustion of XX g of an organic compound gave 0.250.25 g of CO2CO_2 and 0.120.12 g of H2OH_2 O. If the % of carbon is 25%25\% and of hydrogen is 4.89%4.89\%, then X=X = _____ ×10−3\times 10^{-3} g. (Nearest integer) (Molar mass of C, H and O are 12,112, 1 and 1616 g mol−1^{-1} respectively.)

Options

  1. A273273
  2. B2727
  3. C27302730
  4. D227227

Correct answer

A. 273273

Step-by-step solution

Mass of carbon in the compound is calculated from the mass of CO2CO_2 produced:

Mass of C =1244×mass of CO2=1244×0.25=344= \dfrac{12}{44} \times \text{mass of } CO_2 = \dfrac{12}{44} \times 0.25 = \dfrac{3}{44} g

Given that the percentage of carbon in the compound is 25%25\%:

% of C=Mass of CTotal mass X×100\% \text{ of C} = \dfrac{\text{Mass of C}}{\text{Total mass } X} \times 100

25=344X×10025 = \dfrac{\dfrac{3}{44}}{X} \times 100

X=344×10025=344×4=311X = \dfrac{3}{44} \times \dfrac{100}{25} = \dfrac{3}{44} \times 4 = \dfrac{3}{11} g

X≈0.2727X \approx 0.2727 g

Verifying this using the percentage of hydrogen:

Mass of H =218×mass of H2O=218×0.12=175= \dfrac{2}{18} \times \text{mass of } H_2O = \dfrac{2}{18} \times 0.12 = \dfrac{1}{75} g

% of H=175X×100=4.89\% \text{ of H} = \dfrac{\dfrac{1}{75}}{X} \times 100 = 4.89

X=10075×4.89≈0.2727X = \dfrac{100}{75 \times 4.89} \approx 0.2727 g

Thus, X=272.7×10−3X = 272.7 \times 10^{-3} g.

Rounding to the nearest integer, the required value is 273273.

Answer: 273273
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