Quantrex Quantrex AcademyJEE · NEET · NDA PYQs with solutions Open app
99 Percentile Qs Bank for JEE MainChemistryChemical Kinetics

Two reactions, A &#8594; Products &#160;and &#160;B &#8594; Products , have rate constants K a and K b at temperature T and activation energies E a and E b respectively. If K a > K b and E a < E b and assuming that A for both the reactions is same then :

Options

  1. AAt higher temperatures K a will be greater than K b
  2. BAt lower temperature K a and K b will different more and K a > K b
  3. CAs temperature rises K a and K b will be close to each other in magnitude
  4. DNone of these

Correct answer

D. None of these

Step-by-step solution

​​(I) As temperature Rises K a will increase K b will also increase since E a < E b K a >> K b (II) At lower temperature K a will fall K b will fall But as E a < E b K&#39; a > K&#39; b (II) As temperature rises very high K a and K b will try to close each other as they are exponential functions of temperature

Practice Chemical Kinetics on Quantrex Academy →

More from Chemical Kinetics

For a reversible reaction R P , at constant temperature, both the forward and the backward reactions are first order elementary reactions with rate constants k_f and k_b , respecti 2026For a first-order reaction R P at a given temperature, k is the rate constant. For this reaction, at the given temperature, the concentrations of R and P at a time t are [ R ] and 2026Given below are two statements: R=8.314 J K ⁻¹ mol ⁻¹ and 1 cal =4.2 J Statement I: When E_a=12.6 kcal/mol, the room temperature rate constant is doubled by a 10 ,^ C increase in t 2026Decomposition of a hydrocarbon follows the equation k = (5.5 10¹¹ , s ⁻¹) ,e^ -28000 , K T . The activation energy of reaction is __________ kJ mol ⁻¹ . (Nearest Integer) Given : R 2026For a reaction A P at T K , the half life (t_ 1/2 ) is plotted as a function of initial concentration [A]₀ of A as given below. The value of x in the given figure is _______ s (Nea 2026First order gas phase reaction A B + C p_i = initial pressure of gas A, p_t = total pressure of the reaction mixture at time t Expression of rate constant ( k ) is 2026If the half life of a first order reaction is 6.93 minutes then the time required for completion of 99 % of the reaction will be _____ minutes. (Given : 2 = 0.3010 ) 2026Consider the given graph showing variation of reactant concentration with time. Three different reactions were started with identical initial concentration of reactants. Which of t 2026 Full Chemical Kinetics list All 99 Percentile Qs Bank for JEE Main PYQs