99 Percentile Qs Bank for JEE MainChemistryd and f Block Elements
The correct increasing order of basic character of Ce ( OH ) 3 , Gd ( OH ) 3 and Nd ( OH ) 3 is
Options
- ACe ( OH ) 3 < Nd ( OH ) 3 < Gd ( OH ) 3
- BGd ( OH ) 3 < Ce ( OH ) 3 < Nd ( OH ) 3
- CGd ( OH ) 3 < Nd ( OH ) 3 < Ce ( OH ) 3
- DCe ( OH ) 3 < Gd ( OH ) 3 < Nd ( OH ) 3
Correct answer
C. Gd ( OH ) 3 < Nd ( OH ) 3 < Ce ( OH ) 3
Step-by-step solution
Due to lanthanide contraction, as the size of lanthanide ions decreases from left to right La 3 + to   Lu 3 + , the covalent character of the hydroxides increases and hence, the basic strength decreases. So, increasing order of basic characters: Gd ( OH ) 3   < Nd ( OH ) 3   < Ce ( OH ) 3