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99 Percentile Qs Bank for JEE MainChemistryd and f Block Elements

Which of the following statements is TRUE?

Options

  1. ALa ( OH ) 3 is the least basic among hydroxides of lanthanides.
  2. BZr 4+   and   Hf 4+ possess almost the same ionic radii.
  3. CThe oxide Ln 2 O 3 reacts with water to form soluble hydroxides.
  4. DLanthanoids are naturally available.

Correct answer

B. Zr 4+   and   Hf 4+ possess almost the same ionic radii.

Step-by-step solution

Zr   and   Hf both belongs to d - block elements. In d - block elements, the last electron enters into the d - block and due to the poor shielding of f - block elements contraction in the atomic radii as well as ionic radii is observed, therefore both Zr 4+   and   Hf 4+ possess almost the same ionic radii.

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