Quantrex Quantrex AcademyJEE · NEET · NDA PYQs with solutions Open app
JEE Main
Exam
JEE Main
Subject
Chemistry
Chapter
p Block Elements (Group 13 & 14)

JEE Main · Chemistry · p Block Elements (Group 13 & 14)

Aluminium reacts with NaOH and forms compound ' X '. If the...

Aluminium reacts with NaOH\mathrm{NaOH} and forms compound ' XX '. If the coordination number of aluminium in ' XX ' is 6 , the correct formula of XX is

Options

  1. A\left[\mathrm{Al}\left(\mathrm{H}_2 \mathrm{O}\right)_4(\mathrm{OH})_2\right]^{+}
  2. B\left[\mathrm{Al} \left(\mathrm{H}}_{2} \mathrm{O}\right)_3(\mathrm{OH})_3\right]
  3. C\left[\mathrm{Al}\left(\mathrm{H}_2 \mathrm{O}\right)_2(\mathrm{OH})_4\right]^{-}
  4. D\left[\mathrm{Al}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right](\mathrm{OH})_3

Correct answer

C. \left[\mathrm{Al}\left(\mathrm{H}_2 \mathrm{O}\right)_2(\mathrm{OH})_4\right]^{-}

Step-by-step solution

2Al+2NaOH+2H2O⟶2NaAlO2 sodium  meta  aluminate +3H22 \mathrm{Al}+2 \mathrm{NaOH}+2 \mathrm{H}_2 \mathrm{O} \longrightarrow \underset{\substack{\text { sodium } \\ \text { meta } \\ \text { aluminate }}}{2 \mathrm{NaAlO}_2}+3 \mathrm{H}_2 Sodium metaaluminate, thus formed, is soluble in water and changes into the complex \left[\mathrm{Al}\left(\mathrm{H}_2 \mathrm{O}\right)_2(\mathrm{OH})_4\right]^{-},inwhichcoordinationnumberof, in which coordination number of\mathrm{Al}is6.is 6 .
Practice p Block Elements (Group 13 & 14) on Quantrex Academy →

More from p Block Elements (Group 13 & 14)

Given below are two statements : Statement I: Aluminium upon reaction with NaOH forms… JEE Main 2026Consider the following reactions Na_ 2 ~B_ 4 O_ 7 Δ 2 X+ Y CuSO_ 4 + Y Non-Luminous flame… JEE Main 2026It is noticed that Pb^ 2+ is more stable than Pb^ 4+ but Sn^ 2+ is less stable than Sn^… JEE Main 2026The correct statements from the following are : A. Ionic radii of trivalent cations of… JEE Main 2026Given below are two statements : Statement I : Elements ' X ' and ' Y ' are the most and… JEE Main 2026Consider the following reactions. PbCl_ 2 +K_ 2 CrO_ 4 arrow ~A+2 KCl (Hot solution)… JEE Main 2026Given below are two statements : Statement I : The number of pairs among [SiO_ 2 , CO_ 2… JEE Main 2026The group 14 elements A and B have the first ionisation enthalpy values of 708 and 715… JEE Main 2025 Full p Block Elements (Group 13 & 14) list All 99 Percentile Qs Bank for JEE Main PYQs