JEE Main
- Exam
- JEE Main
- Subject
- Chemistry
- Chapter
- p Block Elements (Group 13 & 14)
JEE Main · Chemistry · p Block Elements (Group 13 & 14)
Which one of the following methods is used to prepare carbon...
Which one of the following methods is used to prepare carbon monoxide on commercial scale?
Options
- ADehydration of formic acid with conc.
- BDirect oxidation of C in limited supply of oxygen
- CPassing steam over hot coke
- DHeating lime stone
Correct answer
C. Passing steam over hot coke
Step-by-step solution
(a) When formic acid is dehydrated with (conc.), it gives carbon monoxide (CO) as : \mathrm{HCOOH}+\mathrm{H}_2 \mathrm{SO}_4 \text { (conc.) } \longrightarrow \mathrm{CO}+\mathrm{H}_2 \mathrm{O}+\mathrm{H}_2 \mathrm{SO}_4 But the above process is not used on commercial scale. (b) Direct oxidation of carbon in limited supply of oxygen can give but the process is not used on commercial scale. 2 \mathrm{C}+\mathrm{O}_2 \text { (limited supply) } \longrightarrow 2 \mathrm{CO} (c) When steam is passed over coke , it gives , as : \text { Coke }(\mathrm{C})+\underset{(\text { Steam) }}{\mathrm{H}_2 \mathrm{O}} \stackrel{\Delta}{\mathrm{Ni}} \mathrm{CO}(g)+\mathrm{H}_2(g) The above process can be used to produce (CO) on commercial scale. (d) Lime stone is , on heating it gives oxygen and as : \mathrm{CaCO}_3 \stackrel{\Delta}{\longrightarrow} \mathrm{CaO}+\mathrm{O}_2 Hence, option (c) is the correct answer.