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JEE Main
Exam
JEE Main
Subject
Chemistry
Chapter
p Block Elements (Group 13 & 14)

JEE Main · Chemistry · p Block Elements (Group 13 & 14)

Which one of the following methods is used to prepare carbon...

Which one of the following methods is used to prepare carbon monoxide on commercial scale?

Options

  1. ADehydration of formic acid with conc. H2SO4\mathrm{H}_2 \mathrm{SO}_4
  2. BDirect oxidation of C in limited supply of oxygen
  3. CPassing steam over hot coke
  4. DHeating lime stone

Correct answer

C. Passing steam over hot coke

Step-by-step solution

(a) When formic acid HCOOH\mathrm{HCOOH} is dehydrated with H2SO4\mathrm{H}_2 \mathrm{SO}_4 (conc.), it gives carbon monoxide (CO)andH2Oand \mathrm{H}_2 \mathrm{O} as : \mathrm{HCOOH}+\mathrm{H}_2 \mathrm{SO}_4 \text { (conc.) } \longrightarrow \mathrm{CO}+\mathrm{H}_2 \mathrm{O}+\mathrm{H}_2 \mathrm{SO}_4 But the above process is not used on commercial scale. (b) Direct oxidation of carbon in limited supply of oxygen can give CO\mathrm{CO} but the process is not used on commercial scale. 2 \mathrm{C}+\mathrm{O}_2 \text { (limited supply) } \longrightarrow 2 \mathrm{CO} (c) When steam (H2O)\left(\mathrm{H}_2 \mathrm{O}\right) is passed over coke (C)(\mathrm{C}), it gives CO+H2\mathrm{CO}+\mathrm{H}_2, as : \text { Coke }(\mathrm{C})+\underset{(\text { Steam) }}{\mathrm{H}_2 \mathrm{O}} \stackrel{\Delta}{\mathrm{Ni}} \mathrm{CO}(g)+\mathrm{H}_2(g) The above process can be used to produce (CO) on commercial scale. (d) Lime stone is CaCO3\mathrm{CaCO}_3, on heating it gives oxygen (O2)\left(\mathrm{O}_2\right) and CaO\mathrm{CaO} as : \mathrm{CaCO}_3 \stackrel{\Delta}{\longrightarrow} \mathrm{CaO}+\mathrm{O}_2 Hence, option (c) is the correct answer.
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