JEE Main
- Exam
- JEE Main
- Subject
- Chemistry
- Chapter
- p Block Elements (Group 13 & 14)
JEE Main · Chemistry · p Block Elements (Group 13 & 14)
Among the following oxides, which one is weakly basic and yet a...
Among the following oxides, which one is weakly basic and yet a powerful oxidant?
Options
- A\$(\mathrm{CO}}_{2})
- B\$(\mathrm{SnO}}_{2})
- C\$(\mathrm{SiO}}_{2})
- D\$(\mathrm{PbO}}_{2})
Correct answer
D. \$(\mathrm{PbO}}_{2})
Step-by-step solution
For the dioxides of group- 14 elements (\left(\mathrm{CO}}_{2}, \mathrm{SiO}}_{2}, \mathrm{GeO}}_{2}\right.) and (\left.\mathrm{PbO}}_{2}\right),\mathrm{PbO}}_{2}) is most basic in nature. Again, in oxidation state () in +4 , which is less (\mathrm{PbO}}_{2}) stable than its +2 state because of inert pair effect. So, () of (\mathrm{PbO}}_{2}) has a tendency to be reduced into more stable (\mathrm{Pb}^{2+}) (PbO) showing strong oxidising nature of (\mathrm{PbO}}_{2}).