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JEE Main 202331 JanuaryEvening Shift
Exam
JEE Main
Year
2023
Date
31 January
Shift
Evening Shift
Subject
Chemistry
Chapter
p Block Elements (Group 13 & 14)

JEE Main 2023 · 31 January · Evening Shift · Chemistry · p Block Elements (Group 13 & 14)

The Lewis acid character of boron tri halides follows the order:

The Lewis acid character of boron tri halides follows the order:The Lewis acid character of boron tri halides follows the order:

Options

  1. ABCl3>BF3>BBr3>Bl3{BCl}_{3} > {BF}_{3} > {BBr}_{3} > {Bl}_{3}
  2. BBl3>BBr3>BCl3>BF3{Bl}_{3} > {BBr}_{3} > {BCl}_{3} > {BF}_{3}
  3. CBBr3>Bl3>BCl3>BF3{BBr}_{3} > {Bl}_{3} > {BCl}_{3} > {BF}_{3}
  4. DBF3>BCl3>BBr3>Bl3{BF}_{3} > {BCl}_{3} > {BBr}_{3} > {Bl}_{3}

Correct answer

B. Bl3>BBr3>BCl3>BF3{Bl}_{3} > {BBr}_{3} > {BCl}_{3} > {BF}_{3}

Step-by-step solution

The strength of the acidic character of boron trihalides depends upon π−π\pi - \pi back bonding. In boron trihalides, π−π\pi - \pi -back bonding occurs due to empty orbital of boron and filled orbitals of halogens.

The Lewis acid character of boron tri halides follows the order:

The π−π\pi - \pi back bonding is shown maximum byBF3{BF}_{3}, as the size of B and F are small and comparatively same. Due to this effect tendency of accepting lone-pair of electrons of boron decreases as the size of halogen increases. The order of size of halogens are F<Cl<Br<IF < Cl < Br < I . Thus, acidic nature is in order BF3<BCl3<BBr3<Bl3{BF}_{3} < {BCl}_{3} < {BBr}_{3} < {Bl}_{3}.

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