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JEE Main202226 Jul 2022Morning ShiftChemistryp Block Elements (Group 13 & 14)Actual

Borazine, also known as inorganic benzene, can be prepared by the reaction of 3 -equivalents of " X " with 6 -equivalents of " Y ". " X " and " Y ", respectively are

Options

  1. AB OH 3 and NH 3
  2. BB 2 H 6 and NH 3
  3. CB 2 H 6 and HN 3
  4. DNH 3 and B 2 O 3

Correct answer

B. B 2 H 6 and NH 3

Step-by-step solution

Reaction of ammonia with diborane gives initially B 2 H 6 . 2 NH 3 which is formulated as BH 2 NH 3 2 +   BH 4 -   ; further heating gives borazine, B 3 N 3 H 6 known as ''inorganic benzene'' in view of its ring structure with alternate BH and NH groups. 3 B 2 H 6 + 6 NH 3 → 3 BH 2 NH 3 2 + BH 4 - → Heat 2 B 3 N 3 H 6 + 12 H 2

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