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JEE Main20209 Jan 2020Evening ShiftChemistryp Block Elements (Group 13 & 14)Actual

The reaction of H 3 N 3 B 3 C l 3 A with L i B H 4 in tetrahydrofuran gives inorganic benzene B . Further, the reaction of A with C leads to H 3 N 3 B 3 M e 3 . Compounds B and C respectively, are:

Options

  1. ABogging god M e B r
  2. BDiborane and M e M g B r
  3. CBoron nitride and M e B r
  4. DBorazine and M e M g B r

Correct answer

D. Borazine and M e M g B r

Step-by-step solution

The reaction of H 3 N 3 B 3 C l 3 A with L i B H 4 in tetrahydrofuran gives inorganic benzene B . The reaction is given below. Further, the reaction of compound A reacts with C leads to H 3 N 3 B 3 M e 3 . The reaction is given beow: B 3 N 3 H 3 CI 3 A + LiBH 4 ⟶ B 3 N 3 H 6 B + LiCI + BCI 3 B 3 N 3 H 3 CI 3 A + 3 MeMgBr C ⟶ B 3 N 3 H 3 CH 3 3 + 3 MgBrCI

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