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JEE Main 201419 AprilOnline
Exam
JEE Main
Year
2014
Date
19 April
Mode
Online
Subject
Chemistry
Chapter
p Block Elements (Group 13 & 14)

JEE Main 2014 · 19 April · Online · Chemistry · p Block Elements (Group 13 & 14)

Which of these statements is not true ?

Which of these statements is not true ?

Options

  1. ALiAlH4 is versatile reducing agent in organic synthesis.
  2. BNO+ is isoelectronic with O2
  3. CBoron is always covalent in its compounds
  4. DIn aqueous solution, the Tl+ ion is much more stable than Tl (III)

Correct answer

B. NO+ is isoelectronic with O2

Step-by-step solution

(i) LiAlH4 is a versatile reducing agent
(ii) NO+ (14 electrons), O2(16 electrons) not isoelectronic
(iii) Tl+ is more stable due to Inert pair effect
(iv) Boron compounds are ionic as well

B2O3+2NaOH→2NaBO2+H2O{\text{B}}_{2} {\text{O}}_{3} + 2 NaOH \to 2 {NaBO}_{2} + {\text{H}}_{2} \text{O}
(Sodium meta Borate)
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