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JEE Main 202427 JanuaryEvening Shift
Exam
JEE Main
Year
2024
Date
27 January
Shift
Evening Shift
Subject
Chemistry
Chapter
p Block Elements (Group 15, 16, 17 & 18)

JEE Main 2024 · 27 January · Evening Shift · Chemistry · p Block Elements (Group 15, 16, 17 & 18)

Given below are two statements: Statement (I) : Oxygen being the...

Given below are two statements:

Statement (I) : Oxygen being the first member of group 1616 exhibits only–2– 2 oxidation state.

Statement (II) : Down the group 1616 stability of +4+ 4 oxidation state decreases and +6+ 6 oxidation state increases.

In the light of the above statements, choose the most appropriate answer from the options given below:

Options

  1. AStatement I is correct but Statement II is incorrect
  2. BBoth Statement I and Statement II are correct
  3. CBoth Statement I and Statement II are incorrect
  4. DStatement I is incorrect but Statement II is correct

Correct answer

C. Both Statement I and Statement II are incorrect

Step-by-step solution

Statement-I: Oxygen can have oxidation state from −2- 2 to +2+ 2, so statement I is incorrect

Statement- II: On moving down the group stability of +4+ 4 oxidation state increases whereas stability of +6+ 6 oxidation state decreases down the group, according to inert pair effect.

The inert-pair effect is the tendency of the two electrons in the outermost atomic s-orbital to remain unshared in compounds of post-transition metals.

So both statements are wrong.

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