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JEE Main 20236 AprilMorning Shift
Exam
JEE Main
Year
2023
Date
6 April
Shift
Morning Shift
Subject
Chemistry
Chapter
p Block Elements (Group 15, 16, 17 & 18)

JEE Main 2023 · 6 April · Morning Shift · Chemistry · p Block Elements (Group 15, 16, 17 & 18)

The difference between electron gain enthalpies will be maximum...

The difference between electron gain enthalpies will be maximum between :

Options

  1. ANeNe and FF
  2. BArAr and FF
  3. CNeNe and ClCl
  4. DArAr and ClCl

Correct answer

C. NeNe and ClCl

Step-by-step solution

Electron gain enthalpy is defined as the amount of energy released when an electron is added to an isolated gaseous atom. During the addition of an electron, energy can either be released or absorbed. Electron gain enthalpy decreases down the group because as we move down the group, the size of an element increases, and the effective nuclear charge decreases. Due to this, the incoming electron will experience less attraction. Thus, electron gain enthalpy decreases as we move down the group.

ΔHeg{\Delta H}_{eg} for chlorine=−349kJmole−1= - 349kJ{mole}^{- 1}

ΔHeg{\Delta H}_{eg} for Neon=+116kJmole−1= + 116kJ{mole}^{- 1}

ΔHeg{\Delta H}_{eg} for Argon =+96kJmol−1= + 96{kJmol}^{- 1}

ΔHeg{\Delta H}_{eg}for fluorine =−333kJmol−1= - 333kJ{mol}^{- 1}

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