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Paragraph: Metal nitrate (A) on heating decomposes, leaving a solid residue (B) which goes into solution with dilute HCl . The solution of (B) gives a white precipitate (C) with ammonium carbonate solution. The precipitate (C) is dissolved in dilute HCl and the solution is treated with potassium chromate to get yellow precipitate (D). The solution (B) with dilute H ₂ SO ₄ also gives a white precipitate ( E ) insolubl

Options

  1. ABaSO ₄
  2. BMgSO ₄
  3. CCaSO ₄
  4. DNa ₂ SO ₄

Correct answer

A. BaSO ₄

Step-by-step solution

Lithopone is a white pigment made from a mixture of ZnS and BaSO ₄ ( A ) Ba ( NO ₃ )₂ ( ~B ) BaO +2 NO ₂+ 1 2 O ₂ aligned & BaO +2 HCl BaCl ₂+ H ₂ O & BaCl ₂+ ( NH ₄ )₂ CO ₃ BaCO ₃ ( C )+2 NH ₄ Cl & BaCO ₃+2 HCl BaCl ₂+ CO ₂+ H ₂ O & BaCl ₂+ K ₂ CrO ₄ BaCrO ₄( D )+2 KCl & BaCl ₂+ H ₂ SO ₄ BaSO ₄+2 HCl aligned

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