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JEE Main 202227 JuneEvening Shift
Exam
JEE Main
Year
2022
Date
27 June
Shift
Evening Shift
Subject
Chemistry
Chapter
Practical Chemistry

JEE Main 2022 · 27 June · Evening Shift · Chemistry · Practical Chemistry

Match List I with List II. List-I (Anion) List-II (gas evolved on...

Match List I with List II.

List-I
(Anion)
List-II
(gas evolved on reaction with dil. H2SO4{H}_{2}{SO}_{4})
(A) CO32−{CO}_{3}^{2 -} (I)

Colourless gas which turns lead acetate paper black.

(B) S2−{S}^{2 -} (II)

Colourless gas which turns acidified potassium dichromate solution green.

(C) SO32−{SO}_{3}^{2 -} (III) Brown fumes which turns acidified KI solution containing starch blue.
(D) NO2−{NO}_{2}^{-} (IV) Colourless gas evolved with brisk effervescence, which turns lime water milky.

Choose the correct answer from the options given below

Options

  1. AA−III,B−I,C−II,D−IVA - III, B - I, C - II, D - IV
  2. BA−II,B−I,C−IV,D−IIIA - II, B - I, C - IV, D - III
  3. CA−IV,B−I,C−III,D−IIA - IV, B - I, C - III, D - II
  4. DA−IV,B−I,C−II,D−IIIA - IV, B - I, C - II, D - III

Correct answer

D. A−IV,B−I,C−II,D−IIIA - IV, B - I, C - II, D - III

Step-by-step solution

When small amount of carbonate salt is treated with dilute H2SO4ordilute{H}_{2}{SO}_{4} or diluteHCl,Acolourless,odourlessgas(CO2), A colourless, odourless gas \left({CO}_{2}\right) is evolved with brisk effervescence

When small amount of the following salts are treated with dilute H2SO4{H}_{2}{SO}_{4} the following observations are seen.

Carbonate salt (CO32−)\left({CO}_{3}^{2 -}\right) Brisk effervescence of CO2{CO}_{2} gas, CO32−+H2SO4→SO42−+H2O+CO2↑{CO}_{3}^{2 -} + {H}_{2}{SO}_{4} \to {SO}_{4}^{2 -} + {H}_{2}O + {CO}_{2} ↑
Sulphide salt \left({S}^{- 2}\right)</td><tdstyle="text−align:center;">Acolourlessgas(H2S)</td> <td style="text-align: center;">A colourless gas \left({H}_{2}S\right) with rotten egg smell

Na2S+H2SO4→Na2SO4+H2S↑{Na}_{2}S + {H}_{2}{SO}_{4} \to {Na}_{2}{SO}_{4} + {H}_{2}S ↑

NO2 – on reaction with dilute H2SO4 will give brown NO2(g) will turn KI solution blue.

SO32−{SO}_{3}^{2 -}on reaction with dilute H2SO4{H}_{2}{SO}_{4} will give SO2(g),whichwillturnacidifiedpotassiumdichromatesolutiongreen.</p><p></p>{SO}_{2}\left(g\right), which will turn acidified potassium dichromate solution green.</p><p> </p>

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