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JEE Main 202229 JulyMorning Shift
Exam
JEE Main
Year
2022
Date
29 July
Shift
Morning Shift
Subject
Chemistry
Chapter
Solid State

JEE Main 2022 · 29 July · Morning Shift · Chemistry · Solid State

Ionic radii of cation A ^ + and anion B ^ - are 102 and 181pm...

Ionic radii of cation A+{A}^{+} and anion B−{B}^{-} are 102102 and 181pm181pm respectively. These ions are allowed to crystallize into an ionic solid. This crystal has cubic close packing for B−.A+{B}^{-} . {A}^{+} is present in all octahedral voids. The edge length of the unit cell of the crystal ABAB is___pmpm.

Correct answer

0

Step-by-step solution

In given ionic compound anions form CCP lattice, And cation is present in octahedral void. Means this structure is similar to structure of NaCl. Which is also called rock salt structure.

Edge length = a=?a = ?

In rock salt structure cations and anions are in contact along the edge of the cube.

So, a=2(r++r−)a = 2\left({r}_{+} + {r}_{-}\right)

a=2(102+181)a = 2\left(102 + 181\right)

a=2(283)a = 2\left(283\right)

a=566pma = 566pm

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