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JEE Main 201910 JanuaryEvening Shift
Exam
JEE Main
Year
2019
Date
10 January
Shift
Evening Shift
Subject
Chemistry
Chapter
Solid State

JEE Main 2019 · 10 January · Evening Shift · Chemistry · Solid State

A compound of formula A _ 2 B _ 3 has the HCP lattice. Which atom...

A compound of formula A2B3{A}_{2}{B}_{3} has the HCP lattice. Which atom forms the HCP lattice and what fraction of the tetrahedral voids are occupied by the other atoms?

Options

  1. A

    HCP lattice - BB

    23\dfrac{2}{3}tetrahedral voids - AA

  2. B

    HCP lattice - AA

    13\dfrac{1}{3} tetrahedral voids - BB

  3. C

    HCP lattice - BB

    13\dfrac{1}{3} tetrahedral voids - AA

  4. D

    HCP lattice - AA

    23\dfrac{2}{3} tetrahedral voids - BB

Correct answer

C.

HCP lattice - BB

13\dfrac{1}{3} tetrahedral voids - AA

Step-by-step solution

Atom BB forms HCP as anions are larger in size.

From the formula A2B3{A}_{2}{B}_{3},

Number of BB atoms=3= 3,

Then, number of tetrahedral voids =2×= 2 \timesTetrahedral voids=2×3=6= 2 \times 3 = 6.

As ′A′' A ' is occupying tetrahedral voids,

13\dfrac{1}{3} of tetrahedral voids=13×6=2= \dfrac{1}{3} \times 6 = 2

Therefore, formula of the compound=A2B3= {A}_{2}{B}_{3}

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