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JEE Main 202226 JuneMorning Shift
Exam
JEE Main
Year
2022
Date
26 June
Shift
Morning Shift
Subject
Chemistry
Chapter
Some Basic Concepts of Chemistry

JEE Main 2022 · 26 June · Morning Shift · Chemistry · Some Basic Concepts of Chemistry

On complete combustion 0 . 30g of an organic compound gave 0 . 20g...

On complete combustion 0.30g0 . 30g of an organic compound gave 0.20g0 . 20g of carbon dioxide and 0.10g0 . 10g of water. The percentage of carbon in the given organic compound is____(Nearest Integer)

Correct answer

0

Step-by-step solution

CxHyOz+(x+y4−z2)O2→xCO2+y2H2O{C}_{x}{H}_{y}{O}_{z} + \left(x + \dfrac{y}{4} - \dfrac{z}{2}\right){O}_{2} \to {xCO}_{2} + \dfrac{y}{2}{H}_{2}O\begin{cases}0 . 3g & 0 . 2g & 0 . 1g\end{cases}$</p><p></p><p>\dfrac{{CO}_{2} n}{{H}_{2}O n} = \dfrac{x}{\dfrac{y}{2}} = \dfrac{\dfrac{0 . 2}{44}}{\dfrac{0 . 1}{18}} = \dfrac{9}{11}</p><p></p><p>x = \dfrac{9y}{22}</p><p>Now,</p><p>Now,\dfrac{{C}_{x}{H}_{y}{O}_{2} n}{{CO}_{2} n} = \dfrac{1}{x}</p><p></p><p>⇒ \dfrac{0 . 3}{12x + y + 16z} \times \dfrac{44}{0 . 2} = \dfrac{1}{x}</p><p></p><p>66x = 12x + y + 16z54x = y + 16z</p><p></p><p>\dfrac{54 \times 9y}{22} – y = 16z</p><p></p><p>z = \dfrac{29y}{22}</p><p></p><p>CxHyOz = C\dfrac{9y}{22}{H}_{y}O\dfrac{29y}{22} = {C}_{9}{H}_{22}{O}_{29}</p><p></p><p>% of C = \dfrac{12 \times 9}{\left(12 \times 9 + 22 + 29 \times 16\right)} \times 100 = 18 . 18 %$

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