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JEE Main 20262 AprilMorning Shift
Exam
JEE Main
Year
2026
Date
2 April
Shift
Morning Shift
Subject
Chemistry
Chapter
Thermodynamics (C)

JEE Main 2026 · 2 April · Morning Shift · Chemistry · Thermodynamics (C)

At the transition temperature T , A leftharpoons B and Δ G^0 = 105...

At the transition temperature TT, A⇌BA \rightleftharpoons B and ΔG0=105−35log⁡T\Delta G^0 = 105 - 35\log T where AA and BB are two states of substance XX. The transition temperature in °°C when pressure is 11 atm is _______. (Nearest integer)

Correct answer

0

Step-by-step solution

At the transition temperature and 11 atm pressure, the two states AA and BB are in equilibrium.

For a phase transition of a pure substance at 11 atm, both states are in their standard states, so the reaction quotient Q=1Q = 1.

Using the relation ΔG=ΔG0+RTln⁡Q\Delta G = \Delta G^0 + RT \ln Q, we get ΔG=ΔG0\Delta G = \Delta G^0.

At equilibrium, ΔG=0\Delta G = 0, which implies ΔG0=0\Delta G^0 = 0.

Given ΔG0=105−35log⁡T\Delta G^0 = 105 - 35\log T, we can equate it to zero:

105−35log⁡T=0105 - 35\log T = 0

35log⁡T=10535\log T = 105

log⁡T=3\log T = 3

T=103=1000T = 10^3 = 1000 K

Converting the temperature to Celsius:

T(∘C)=1000−273=727∘CT(^{\circ}\text{C}) = 1000 - 273 = 727^{\circ}\text{C}

Answer: 727727
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