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JEE Main 202623 JanuaryMorning Shift
Exam
JEE Main
Year
2026
Date
23 January
Shift
Morning Shift
Subject
Chemistry
Chapter
Thermodynamics (C)

JEE Main 2026 · 23 January · Morning Shift · Chemistry · Thermodynamics (C)

A cup of water at 5^ C (system) is placed in a microwave oven and...

A cup of water at 5∘C5^{\circ} \mathrm{C} (system) is placed in a microwave oven and the oven is turned on for one minute during which the water begins to boil. Which of the following option is true ?

Options

  1. Aq=+ve,w=0,ΔU=−ve\mathrm{q}=+\mathrm{ve}, \mathrm{w}=0, \Delta \mathrm{U}=-\mathrm{ve}
  2. Bq=+ve,w=−ve,ΔU=−ve\mathrm{q}=+\mathrm{ve}, \mathrm{w}=-\mathrm{ve}, \Delta \mathrm{U}=-\mathrm{ve}
  3. Cq=−ve,w=−ve,ΔU=−ve\mathrm{q}=-\mathrm{ve}, \mathrm{w}=-\mathrm{ve}, \Delta \mathrm{U}=-\mathrm{ve}
  4. Dq=+ve,w=−ve,ΔU=+ve\mathrm{q}=+\mathrm{ve}, \mathrm{w}=-\mathrm{ve}, \Delta \mathrm{U}=+\mathrm{ve}

Correct answer

D. q=+ve,w=−ve,ΔU=+ve\mathrm{q}=+\mathrm{ve}, \mathrm{w}=-\mathrm{ve}, \Delta \mathrm{U}=+\mathrm{ve}

Step-by-step solution

For water heating in a microwave:
Heat (q): The microwave radiates electromagnetic energy that is absorbed by water molecules, so q = +ve
Work (w): As water heats and boils, it expands against atmospheric pressure. The system does work on the surroundings, so w = -ve
Internal Energy (ΔU): From the first law, ΔU = q + w. Since heat absorbed (+ve) is much larger in magnitude than work done against atmosphere (-ve), the net change is ΔU = +ve (confirmed by temperature increase from 5°C to boiling)
Therefore: q = +ve, w = -ve, ΔU = +ve
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