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JEE Main 20257 AprilMorning Shift
Exam
JEE Main
Year
2025
Date
7 April
Shift
Morning Shift
Subject
Chemistry
Chapter
Thermodynamics (C)

JEE Main 2025 · 7 April · Morning Shift · Chemistry · Thermodynamics (C)

Total enthalpy change for freezing of 1 mol of water at 10^ C to...

Total enthalpy change for freezing of 1 mol of water at 10∘C10^{\circ} \mathrm{C} to ice at −10∘C-10^{\circ} \mathrm{C} is ____
(Given : Δfus H=x kJ/mol\Delta_{\text{fus }} H=x \mathrm{~kJ} / \mathrm{mol})
Cp[H2O(l)]=yJmol−1 K−1Cp[H2O(s)]=zJmol−1 K−1\begin{aligned} & \mathrm{C}_{\mathrm{p}}\left[\mathrm{H}_2 \mathrm{O}(\mathrm{l})\right]=\mathrm{y} \mathrm{J} \mathrm{mol}^{-1} \mathrm{~K}^{-1} \\ & \mathrm{C}_{\mathrm{p}}\left[\mathrm{H}_2 \mathrm{O}(\mathrm{s})\right]=\mathrm{z} \mathrm{J} \mathrm{mol}^{-1} \mathrm{~K}^{-1}\end{aligned}

Options

  1. A−x−10y−10z-x-10 y-10 z
  2. B−10(100x+y+z)-10(100 x+y+z)
  3. C10(100x+y+z)10(100 x+y+z)
  4. Dx−10y−10zx-10 y-10 z

Correct answer

B. −10(100x+y+z)-10(100 x+y+z)

Step-by-step solution

ΔH=1×y(0−10)−x×1000+1×z(−10∘−0∘)ΔH=−10(100x+y+z) Joule. \begin{aligned} & \Delta H=1 \times y(0-10)-x \times 1000+1 \times z\left(-10^{\circ}-0^{\circ}\right) \\ & \Delta H=-10(100 x+y+z) \text{ Joule. }\end{aligned}
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